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Eurasian Journal of Physics and Functional Materials. 2023; 7: 38-44

Electron-hole trapping centers in Na2SO4 with a transition metal impurity Mn

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https://doi.org/10.32523/ejpfm.2023070102

Аннотация

The Na2SO4 samples were obtained by slow evaporation method. The mechanisms of the formation of electron and hole trapping centers are investigated by spectroscopic methods. Intrinsic recombination emission of 2.9–3.1 eV and impurity emission of 1.85 eV are excited at 4.0–4.5 eV. Intrinsic SO3−4−SO4 and impurity Mn+ − SO4 trapping centers were revealed. The local levels corresponding between the electron and hole trapping center are 4.0–4.5 eV. The decay of intrinsic and impurity trapping centers was recorded at temperatures of 130–150 K and 280–350 K.

Список литературы

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Eurasian Journal of Physics and Functional Materials. 2023; 7: 38-44

Electron-hole trapping centers in Na2SO4 with a transition metal impurity Mn

Nurakhmetov T.N. , Alibay T.T. , Pazylbek S. , Zhunusbekov A.M. , Sadykova B.M. , Tolekov D.A. , Shamieva R.K. , Nurpeissov A.S.

https://doi.org/10.32523/ejpfm.2023070102

Abstract

The Na2SO4 samples were obtained by slow evaporation method. The mechanisms of the formation of electron and hole trapping centers are investigated by spectroscopic methods. Intrinsic recombination emission of 2.9–3.1 eV and impurity emission of 1.85 eV are excited at 4.0–4.5 eV. Intrinsic SO3−4−SO4 and impurity Mn+ − SO4 trapping centers were revealed. The local levels corresponding between the electron and hole trapping center are 4.0–4.5 eV. The decay of intrinsic and impurity trapping centers was recorded at temperatures of 130–150 K and 280–350 K.

References

1. J. Manam, S. Das, Solid state sciences 12(8) (2010) 1435–1444.

2. L. Daling et al., Radiation measurements 30(1) (1999) 59–63.

3. Z. Chunxiang et al., Radiation measurements 32(2) (2000) 123–128.

4. B.V.R. Chowdari, P. Venkateswarlu, J. Chem. Phys. 48 (1968) 318–322.

5. T. Koketai et al., Physics Procedia 76 (2015) 97–100.

6. V.S. Osminin, V.G. Plekhanov, N.I. Silkin, Journal of Applied Spectroscopy 21 (1974) 908–910.

7. R. Majgier, G. Okada, Journal of Luminescence 257 (2023) 119702.

8. T.N. Nurakhmetov et al., Proceedings of 8th International Congress on Energy Fluxes and Radiation Effects / Edited by Dr. Dmitry Sorokin and Anton Grishkov (Tomsk: TPU Publishing House, 2022) 1139.

9. S.T. Taide, N.B. Ingale, S.K. Omanwar, Appl Phys 7(3) (2015) 27–32.

10. T.N. Nurakhmetov et al., Optik 242 (2021) 167081.

11. T.N. Nurakhmetov et al., Eurasian Journal of Physics and Functional Materials 5(3) (2021) 235–241.

12. T.N. Nurakhmetov et al., Eurasian Journal of Physics and Functional Materials 5(2) (2021) 140–147.

13. T.N. Nurakhmetov et al., Eurasian Journal of Physics and Functional Materials 5(3) (2021) 200–208.

14. T.N. Nurakhmetov et al., Eurasian journal of physics and functional materials 5(1) (2021) 24–30.

15. B.N. Yussupbekova et al., Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 481 (2020) 19–23.

16. S.R. Nair et al., Journal of Physics: Condensed Matter 9 (1997) 8307.