Вестник КазНУ. Серия химическая. 2020; 97: 10-15
Получение люминесцентного материала на основе NaBaY(BO3)2, легированного ионами тербия и европия
https://doi.org/10.15328/cb1122Аннотация
Новый люминесцентный материал на основе сложного бората NaBaY(BO3)2, легированный ионами Tb3+ и Eu3+, получен методом высокотемпературного твердофазного синтеза. Методом рентгенофазового анализа показано, что NaBaY(BO3)2:0,07Tb3+:0,1Eu3+ кристаллизуется в тригональной сингонии с пространственной группой R-3m и изотипно минералу бючлииту K2Ca(CO3)2. Кристаллическая структура люминофора является слоистой, сформированной из [BO3] треугольников, [YO6] октаэдров, [BaO9] и [NaO9] полиэдров. Рассчитанные значения параметров элементарной ячейки составляют для NaBaY(BO3)2:0,07Tb3+:0,1Eu3+: a=5,3510(6) Å, c=17,9338(3) Å, V=444,71(2) Å3. Исследованы люминесцентные свойства NaBaY(BO3)2:0,07Tb3+:0,1Eu3+.
Список литературы
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Chemical Bulletin of Kazakh National University. 2020; 97: 10-15
Obtaining of luminescent material based on NaBaY(BO3)2 doped with terbium and europium ions
https://doi.org/10.15328/cb1122Abstract
A new luminescent material based on complex borate NaBaY(BO3)2 doped with Tb3+ and Eu3+ ions was obtained by high-temperature solid-state synthesis. Using X-ray diffraction analysis it was shown that NaBaY(BO3)2:0.07Tb3+:0.1Eu3+ crystallizes in trigonal system with the space group R-3m and isotypic with the mineral buetschliit K2Ca(CO3)2. The crystal structure of the phosphor is layered, formed from [BO3] triangles, [YO6] octahedra, [BaO9] and [NaO9] polyhedra. The calculated unit cell parameters for NaBaY(BO3)2:0.07Tb3+:0.1Eu3+ are: a=5.3510(6) Å, c=17.9338(3) Å, V=444.71(2) Å3. The luminescent properties of NaBaY(BO3)2:0.07Tb3+:0.1Eu3+ were studied.
References
1. Chen C, Wu Y, Jiang A, Wu B, You G, et al (1989) J Opt Soc Am B 6:616-621. https://doi.org/10.1364/JOSAB.6.000616
2. Cheng LK, Bosenberg W, Tang CL (1988) J Cryst Growth 89:553-559. https://doi.org/10.1016/0022-0248(88)90218-7
3. Jiang H, Li J, Wang J, Hu XB, Liu H, Teng B, Wang P (2001) J Cryst Growth 233:248-252. https://doi.org/10.1016/S0022-0248(01)01562-7
4. Wang DY, Chen TM, Cheng BM (2012) Inorg Chem 51:2961-2965. https://doi.org/10.1021/ic202241h
5. Wu Y, Ding D, Pan S, Yang F, Ren G (2011) Opt Mater 33:655-659. https://doi.org/10.1016/j.optmat.2010.11.024
6. Kuznetsov AB, Kokh KA, Kononova NG, Shevchenko VS, Rashchenko SV, et al (2020) J Lumin 217:116755. https://doi.org/10.1016/j.jlumin.2019.116755
7. Chen X, Zhang F, Shi Y, Sun Y, Yang Z, Pan S (2018) Dalton Trans 47:750-757. https://doi.org/10.1039/C7DT04223J
8. Li RK, Wu CC, Xia MJ (2016) Opt Mater 62:452-457. https://doi.org/10.1016/j.optmat.2016.10.025
9. Chen P, Xia M, Li RK (2015) New J Chem 39:9389-9395. https://doi.org/10.1039/C5NJ01913C
10. Xia M, Zhai K, Lu J, Sun Y, Li RK (2017) Inorg Chem 56:8100-8105. https://doi.org/10.1021/acs.inorgchem.7b00756
11. Mutailipu M, Xie Z, Su X, Zhang M, Wang Y, Yang Z, Pan S (2017) J Am Chem Soc 139:18397-18405. https://doi.org/10.1021/jacs.7b11263
12. Xie Z, Mutailipu M, He G, Han G, Wang Y, Yang Z, Pan S (2018) Chem Mater 30:2414-2423. https://doi.org/10.1021/acs.chemmater.8b00491
13. Kuznetsov AB, Ezhov DM, Kokh KA, Kononova NG, Shevchenko VS, et al (2018) Mater Res Bull 107:333-338. https://doi.org/10.1016/j.materresbull.2018.07.037
14. Kuznetsov AB, Ezhov DM, Kokh KA, Kononova NG, Shevchenko VS, et al (2019) J Cryst Growth 519: 54-59. https://doi.org/10.1016/j.jcrysgro.2019.05.007
15. Uralbekov B, Shevchenko V, Kuznetsov A, Kokh A, Kononova N, et al (2019) J Lumin 216:116712. https://doi.org/10.1016/j.jlumin.2019.116712
16. Seryotkin YV, Bakakin VV, Kokh AE, Kononova NG, Svetlyakova TN, et al (2010) J Solid State Chem 183:1200-1204. https://doi.org/10.1016/j.jssc.2010.03.005
17. Svetlyakova TN, Kokh AE, Kononova NG, Fedorov PP, Rashchenko SV, Maillard A (2013) Crystallogr Rep 58:54-60. https://doi.org/10.1134/S1063774513010136
18. Kononova N, Shevchenko V, Kokh A, Nabeeva T, Chapron D, et al (2016) Mater Res 19:834-838. https://doi.org/10.1590/1980-5373-MR-2016-0081
19. Kokh AE, Kononova NG, Shevchenko VS, Seryotkin YV, Bolatov AK, et al (2017) J Alloys Comp 711:440-445. https://doi.org/10.1016/j.jallcom.2017.03.322
20. Eurasian Patent №025559. The photoluminescent material of rare-earth orthoborate and method for its production [Fotolyuminestsentnyy material redkozemel’nogo ortoborata i sposob yego polucheniya]/ Kokh AE, Kononova NG, Shevchenko VS, Seryotkin YV, Bolatov AK, Uralbekov BM, Burkitbayev M: published 30.01.2017, № 1’2017. (In Russian)
21. Gao J, Song L, Hu X, Zhang D (2011) Solid State Sci 13:115-119. https://doi.org/10.1016/j.solidstatesciences.2010.10.021
22. Kononova NG, Shevchenko VS, Kokh AE, Bolatov AK, Uralbekov BM, et al (2017) Cryst Res Technol 52:1700024. https://doi.org/10.1002/crat.201700024
23. Akella A, Keszler DA (1995) Mater Res Bull 30:105-111. https://doi.org/10.1016/0025-5408(94)00113-8
24. Tang H, Li Y, Yang R, Gao W (2019) J Lumin 208:253-258. https://doi.org/10.1016/j.jlumin.2018.12.058
25. Geng W, Zhou X, Ding J, Wang Y (2018) J Am Ceram Soc 101:4560-4571. https://doi.org/10.1111/jace.15693
26. Peng Y, Lian Z, Zhang L, Shen G, Wang X, Yan Q (2014) Mater Express 4:533-538. https://doi.org/10.1166/mex.2014.1195
27. Freidzon AY, Kurbatov IA., Vovna VI (2018) Phys Chem Chem Phys 20:14564-14577. https://doi.org/10.1039/C7CP08366A
